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Conformational preference of substituted naphthalenes. 2—proton–proton coupling constants of hydroxy derivatives of naphthalene

✍ Scribed by Salman R. Salman

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
250 KB
Volume
22
Category
Article
ISSN
0749-1581

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✦ Synopsis

Long-range proton-proton coupling constants between the hydroxy proton and ring protons were employed to deduce the confomtional preferences of 1-and 2-hydroxynaphthalene. 2,6-Dibromo-1,5-dihydroxynaphthalene, 2-acetyl-l-hydroxynaphthalene, 1,6-dibromo-2-hydroxynaphthalene and 2-hydroxy-1-naphthaldehyde were used as model compounds. Molecular orbital calculations at the CND0/2 and JNDO level were used to calculate the energy and the long-range proton-proton coupling of different conformers of 1and 2-hydroxynaphthalene.

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