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Stereochemical studies: XVII—the proton coupling constants and conformational equilibria of trans-1,2-disubstituted cyclohexenes

✍ Scribed by N. M. Viktorova; S. P. Knyazev; N. S. Zefirov; Yu. D. Gavrilov; G. M. Nikolaev; V. F. Bystrov

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
331 KB
Volume
6
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The vicinal ^3^J~aa~ and ^3^J~ee~ spin‐spin coupling constants of a number of deuterated trans‐1,2‐disubstituted cyclohexenes and the Δ__H__ and Δ__S__ values of the conformational equilibria of these compounds have been determined by computer optimisation of the ^3^J(HH) = f(T) function. Compounds with —CF~3~ and CCl~3~ substituents were shown to have an enhanced proportion of the diaxial conformer.

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