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Conformational isomerism in dihydropyran. Conjugative stabilization of the half-chair conformer

✍ Scribed by C.Hackett Bushweller; James W. O'Neil

Book ID: 104240117
Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 167 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)88791-8

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✦ Synopsis

The various roles of the lone pair in the conformational dynamics and preferences of medium heterocycles are not clearly defined (11, although certain cases seem clear, e.g., the "E-axial effect" (2).

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