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Conformational equilibrium in substituted benzyl alcohols

✍ Scribed by V. A. Granzhan; Ya. A. Shuster; N. A. Barba; K. F. Kentéńaru; L. S. Chasovskikh; S. F. Manole

Publisher
Springer US
Year
1974
Tongue
English
Weight
292 KB
Volume
20
Category
Article
ISSN
0021-9037

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Permanganate, solubilized in methylene chloride with the aid of a phase transfer agent, oxidizes benzyl alcohol to benzaldehyde and bcnzyl ethers to benzoate esters. Although the rate of oxidation of the ether is about an order of magnitude slower than alcohol oxidation, both respond in an identical