The kinetics of the oxidation of six substituted phenethyl alcohols by sodium N-chlorobenzenesulphonamide or chloramine-B (CAB) in the presence of HCI was studied at 35 "C. The rate shows a first order dependence on [CABIo and [H'] and is of fractional order in [PEA], and [Cl-1. Ionic strength varia
Oxidation of Substituted Benzyl Alcohols by Quinoxalinium Dichromate. A Kinetic Study
✍ Scribed by Beytiye Özgün; Nebahat Değirmenbaşı
- Publisher
- Springer Vienna
- Year
- 2004
- Tongue
- English
- Weight
- 153 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0026-9247
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The kinetics of the oxidation of six substituted phenethyl alcohols by sodium N-chlorobenzenesulphonamide or chloramine-B (CAB) in the presence of HCI was studied at 35 "C. The rate shows a first-order dependence on [CAB],, and [H+] and is fractional order in [PEA], and [Cl-1. Ionic strength variati
Permanganate, solubilized in methylene chloride with the aid of a phase transfer agent, oxidizes benzyl alcohol to benzaldehyde and bcnzyl ethers to benzoate esters. Although the rate of oxidation of the ether is about an order of magnitude slower than alcohol oxidation, both respond in an identical