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Conformational Change Induced Reversible Assembly/Disassembly of Poly-L-lysine-Functionalized Gold Nanoparticles

✍ Scribed by Guo, Y.; Ma, Y.; Xu, L.; Li, J.; Yang, W.


Book ID
121409993
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
216 KB
Volume
111
Category
Article
ISSN
1932-7447

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πŸ“œ SIMILAR VOLUMES


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## Abstract Transient electric birefringence measurements on poly(L‐lysine hydrobromide) in methanol–water mixtures have been carried out at various solvent compositions in the vicinity of the helix–coil transition region (from 87 to 98 vol % methanol). Anomalous birefringence transients were obser

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Poly-L-lysine exists as an a-helix at high pH and a random coil at neutral pH. When the a-helix is heated above 27ЊC, the macromolecule undergoes a conformational transition to a b-sheet. In this study, the stability of the secondary structure of poly-L-lysine in solutions subjected to shear flow, a