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Conformational behavior of polyethylenimine derivatives revealed by fluorescence spectroscopy

✍ Scribed by Robert A. Pranis; Irving M. Klotz

Publisher
Wiley (John Wiley & Sons)
Year
1977
Tongue
English
Weight
790 KB
Volume
16
Category
Article
ISSN
0006-3525

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✦ Synopsis

Abstract

Conformation behavior of polyethylenimine has been examined by studies of the fluorescence characteristics of derivatives of the polymer containing pyrenyl ligands. Excimer formation within the macromolecular matrix serves as a sensitive probe of group proximities. The experimental observations combined with nearest neighbor analyses lead to quantitative assessments of the extent of interaction between polymer side chains.

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