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Conformational Behavior of C-Glycosyl Analogues of Sialyl-α-(2→3)-Galactose

✍ Scribed by Ana Poveda; Juan Luis Asensio; Tülay Polat; Hélèn Bazin; Robert J. Linhardt; Jesús Jiménez-Barbero

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 539 KB
Volume: 2000
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(200005)2000:9<1805::aid-ejoc1805>3.0.co;2-a

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✦ Synopsis

The conformational behavior of the C-glycosyl analogue of sialyl-α-(2Ǟ3)-galactose, synthesized as a glycosidase inhibitor, has been studied using a combination of NMR spectroscopy (J and NOE data) and molecular dynamics calculations. The obtained results show that the population distribution of conformers with respect to the orientation about the [a]

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