ChemInform Abstract: A Convergent Synthesis of α-C-1,3-Mannobioside via SmI2-Promoted C-Glycosylation.
✍ Scribed by Sussie L. Krintel; Jesus Jimenez-Barbero; Troels Skrydstrup
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
The synthesis of the C-glycoside analogue of the disaccharide Man-(a1 32)Man has been achieved in a highly stereoselective and efficient manner employing an approach which closely parallels O-glycoside synthesis. The key step included the samarium diiodide reduction of mannosyl pyridylsulfone 18 in