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ChemInform Abstract: A Convergent Synthesis of α-C-1,3-Mannobioside via SmI2-Promoted C-Glycosylation.

✍ Scribed by Sussie L. Krintel; Jesus Jimenez-Barbero; Troels Skrydstrup


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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📜 SIMILAR VOLUMES


Samarium Diiodide Promoted C-Glycosylati
✍ Olivier Jarreton; Troels Skrydstrup; Juan-Félix Espinosa; Jesús Jiménez-Barbero; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 223 KB 👁 2 views

The synthesis of the C-glycoside analogue of the disaccharide Man-(a1 32)Man has been achieved in a highly stereoselective and efficient manner employing an approach which closely parallels O-glycoside synthesis. The key step included the samarium diiodide reduction of mannosyl pyridylsulfone 18 in