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Conformational Analysis. XXXIX. The Conformations of Ring A in Bromo Derivatives of Cholestan-3-one and Related Compounds 1,2

✍ Scribed by Allinger, Norman L.; Carpenter, John G. D.; DaRooge, Margaret A.


Book ID
126046852
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
946 KB
Volume
30
Category
Article
ISSN
0022-3263

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## Abstract A mixture of stereoisomers of 2,4‐dimethoxybicyclo[3.3.1]nonan‐9‐one was prepared, separated by column chromatography and characterized by 60 MHz ^1^H NMR spectroscopy using Eu(fod)~3~. A double chair conformation with axial methoxyl groups is established for (1__R__,2__S__,4__R__,5__S_