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Conformational analysis of bicyclo[3.3.1]nonane-exo-2,exo-4-dicarboxylic acid derivatives and related compounds

✍ Scribed by Camps, Pelayo ;Castañé, Joan ;Feliz, Miguel ;Jaime, Carlos ;Minguillón, Cristina


Publisher
Wiley (John Wiley & Sons)
Year
1989
Tongue
English
Weight
1006 KB
Volume
122
Category
Article
ISSN
0009-2940

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The conformation of (1R,2S,4R,5S)-2,4-di
✍ P. Camps; C. Jaime 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 366 KB

## Abstract A mixture of stereoisomers of 2,4‐dimethoxybicyclo[3.3.1]nonan‐9‐one was prepared, separated by column chromatography and characterized by 60 MHz ^1^H NMR spectroscopy using Eu(fod)~3~. A double chair conformation with axial methoxyl groups is established for (1__R__,2__S__,4__R__,5__S_