per-compounds (acyclic compounds) P 0390 ## 10 -084 A Novel Organic Peroxyester as an Exclusive Source of tert-Butyl Radicals. -Kinetic data of the thermolysis of (IV) in cumene show that the decomposition rate-constant is three times higher than that of tert-butyl peroxypivalate. Radical trappin
Conformational analysis of t-butyl peroxyesters of organic acids
โ Scribed by N. A. Turovskii; A. A. Turovskii; N. V. Dzumedzei
- Book ID
- 104922806
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1977
- Tongue
- English
- Weight
- 139 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0022-4766
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๐ SIMILAR VOLUMES
Chemical equilibrations of transand cis-4-t-butyl-2-~thylcyclohexanones (1 and 2) have -\_ . shown that 2 is more stable than A, AC0 = -1.7 f 0.1 kcal/mle at 4D\*.4\*5 The equilibrations 1" e z,e and 35 \* 4~. if exclusively between the chair conformations shown, should give nearly "3 k C(CH3)3 le
Although the hydrochloride of c-4-t-butyl-l-phenyl-c-l-(N-piperidyl)cyclohexane crystallizes in the conformation with axial-t-butyl, it exists as an almost equimolar mixture of the two chair conformers in CD-Cl\_ solution. -The nosition of eauilibrium allows one to calculate AG:-Bu as -4.9 kcal/mol.