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ChemInform Abstract: A Novel Organic Peroxyester as an Exclusive Source of tert-Butyl Radicals.

✍ Scribed by T. NAKAMURA; Y. WATANABE; H. TEZUKA; W. K. BUSFIELD; I. D. JENKINS; E. RIZZARDO; S. H. THANG; S. SUYAMA

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199810084

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✦ Synopsis

per-compounds (acyclic compounds) P 0390

10 -084

A Novel Organic Peroxyester as an Exclusive Source of tert-Butyl Radicals.

-Kinetic data of the thermolysis of (IV) in cumene show that the decomposition rate-constant is three times higher than that of tert-butyl peroxypivalate. Radical trapping techniques show that the thermolysis of (IV) in cumene generates tert-butyl radicals exclusively. -(NAKAMURA,

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