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Conformational analysis of cis- and trans-2,6-diphenyl-5,6-dihydro-2H-thiopyran

โœ Scribed by Henrichs, P. M.; Chen, C. H.

Book ID
127159330
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
529 KB
Volume
44
Category
Article
ISSN
0022-3263

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Some 2-alkyl-4-methyl-2,6-diphenyl-2H-thiopyrans were synthesized, and the crystal structure of 2-tert-butyl-4-methyl-2,6-diphenyl-2Hthiopyran 1 was determined by single-crystal X-ray diffraction. X-ray crystallographic analysis and ab initio HF/6-31G(d) and B3LYP/6-31G(d) calculations revealed a fa