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Conformational analysis of 5-thio-D-glucose

✍ Scribed by Lambert, Joseph B.; Wharry, Stephen M.


Book ID
126834888
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
534 KB
Volume
46
Category
Article
ISSN
0022-3263

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Three routes were investigated for the conversion of D-glucose into the title compound. In the first approach, reduction of the 5,6-thiirane ring of 5,6-dideoxy-5,6-epithio-1,2-O-isopropylidene-t~-D-glucofuranose (17) as well as that of its 3-O-allyl derivative (13) with lithium aluminium hydride wa