ABSTRAm 5,6-Anhydro-1,2-0-isopropylidene-3-O-methanesulphonyl-a-~-idofuranose was converted, via the related gZucod$-episulphide, into 6-0-acetyl-5-S-acetyl-1,2-O-isopropylidene-3-O-methanesulphonyl-5-thio-at-D-glucofuranose (9). Replacement of the acetyl groups of 9, or the related 3-toluene-p-sulp
โฆ LIBER โฆ
5-Thiopyranoses. Part 11. Isopropylidene acetals of 5-thio-D-glucose, 5-thio-D-allose, and 5-thio-D-altrose and some of their methyl glycosides
โ Scribed by Al-Masoudi, Najim A. L.; Hughes, Neil A.
- Book ID
- 121457898
- Publisher
- Royal Society of Chemistry
- Year
- 1987
- Weight
- 973 KB
- Category
- Article
- ISSN
- 1472-7781
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Acid-catalysed methanolysis of 6-0-acetyl-5-S-acetyl-1,2-O-isopropylidene-5-thio-3-0-toluene-p-sulphonyl-a-D-glucofuranose gave the methyl 5-thio-3-0toluene-p-sulphonyl-a-and -/3-D-glucopyranosides (5). Treatment of 5 with acidified 2,2-dimethoxypropane and then sodium methoxide gave the methyl 2,3a