𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Conformational analysis of 2-halotetrahydrothiopyran S-oxides. Diminution of the anomeric effect in S(O)-C-X compared to S-C-X segments.

✍ Scribed by Eusebio Juaristi; Mario Ordoñez


Book ID
108372440
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
790 KB
Volume
50
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Conformational analysis of 2-(diphenylph
✍ Mario Ordóñez; Eusebio Juaristi 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 365 KB

The conformational preference of the diphenylphosphinoyl group at the alpha position in the thiane ring was estimated by low temperature NMR, AG~raK = + 0.46 + 0.11 kcal/mol, and at 50°C, via chemical equilibration 0 of anancomeric models, AGa2aK = -0.26 +\_ 0.10 kcal/mol. These thermodynamic data a