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Conformational analysis of 1,3-dithian-2-yltrimethylphosphonium chloride. Origin of the S-C-P anomeric effect

✍ Scribed by Juaristi, Eusebio; Cuevas, Gabriel


Book ID
126783013
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
466 KB
Volume
115
Category
Article
ISSN
0002-7863

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Conformational analysis of 2-(diphenylph
✍ Mario OrdΓ³Γ±ez; Eusebio Juaristi πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 365 KB

The conformational preference of the diphenylphosphinoyl group at the alpha position in the thiane ring was estimated by low temperature NMR, AG~raK = + 0.46 + 0.11 kcal/mol, and at 50Β°C, via chemical equilibration 0 of anancomeric models, AGa2aK = -0.26 +\_ 0.10 kcal/mol. These thermodynamic data a