Conformational analysis of 1-acetyl-2-methylhydrazine
✍ Scribed by O Tšubrik; P Burk; T Pehk; U Mäeorg
- Book ID
- 114141527
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 110 KB
- Volume
- 546
- Category
- Article
- ISSN
- 0166-1280
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Conformational studies of acetylated open chain hexitol derivatives, possessing similar structures but differing in their configuration have been made by analysing their NMR spectra. It is shown, that the carbon chain of all three (manno-, ido-and gluco-) isomers is present in a non planar non zigza
## Abstract Tautomerism in aromatic systems with oxygen substitutents is rare. This is investigated in 2‐acetyl‐1,8‐dihydroxy‐3,6‐dimethylnaphthalene (1) and in 2,7‐diacetyl‐1,8‐dihydroxy‐3,6‐dimethylnaphthalene (2). The tautomeric nature of 2‐acetyl‐1,8‐dihydroxy‐3,6‐dimethylnaphthalene is support