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Conformational analysis of 1,2:5,6-diepithio-3,4-di-o-acetyl-hexitols

✍ Scribed by P. Sohár; J. Kuszmann

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
323 KB
Volume
3
Category
Article
ISSN
0749-1581

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✦ Synopsis

Conformational studies of acetylated open chain hexitol derivatives, possessing similar structures but differing in their configuration have been made by analysing their NMR spectra. It is shown, that the carbon chain of all three (manno-, ido-and gluco-) isomers is present in a non planar non zigzag conformation, containing the acetoxy groups at C-3 and C-4 in a trans relation.

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