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Conformational Analysis and Near-Infrared-Induced Rotamerization of Malonic Acid in an Argon Matrix

✍ Scribed by Maçôas, Ermelinda M. S.; Fausto, Rui; Lundell, Jan; Pettersson, Mika; Khriachtchev, Leonid; Räsänen, Markku

Book ID
120047777
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
93 KB
Volume
104
Category
Article
ISSN
1089-5639

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✍ Stefan Sander; Helge Willner; Leonid Khriachtchev; Mika Pettersson; Markku Räsän 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 103 KB

A cis/trans equilibrium mixture of matrix-isolated oxalyl fluoride was irradiated with a narrowband tunable IR source in the 2 (CO) spectral region (3680 -3710 cm Ϫ1 ). Rotamerization of cis into trans and vice versa was achieved (even site selective) by selective IR pumping. The experiments strongl