A cis/trans equilibrium mixture of matrix-isolated oxalyl fluoride was irradiated with a narrowband tunable IR source in the 2 (CO) spectral region (3680 -3710 cm ฯช1 ). Rotamerization of cis into trans and vice versa was achieved (even site selective) by selective IR pumping. The experiments strongl
Thermal and CO-laser induced rotamerization of CH2ClCOOH in an argon matrix
โ Scribed by A. Kulbida; A. Nosov
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 517 KB
- Volume
- 265
- Category
- Article
- ISSN
- 0022-2860
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