## Abstract The linear free energy relationship of __Sicher__ for relative reactivity towards chromic acid oxidation (ΞΞ__G__) as a function of thermodynamic stability (Ξ__G__) has been reexamined with 23 pairs of epimeric alcohols. The plot of Ξ__G__ __vs__. Ξ__G__ has a slope of 0.8, a correlatio
β¦ LIBER β¦
Conformational analysis and chromic acid oxidation. The rationalization of the rates of oxidation of secondary alcohols
β Scribed by Mueller, Paul; Perlberger, Jean C.
- Book ID
- 125935325
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 733 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0002-7863
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Strong evidence has accumulated in favor of a conformation for the erythronolide rin& the nucleus of the erythromycin antibiotics, which is approximated by the stereoformula L. '-' This and 2, R,+R,= 0 i.1 R,=OH, R3 =H 5, R,=H, R,=OH closely related3 three-dimensional arrangements lie in a deep well