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Conformation preference of 5-nitro group in 1,3-dioxanes

✍ Scribed by B. A. Arbuzov; E. N. Klimovitskii; L. K. Yuldasheva; A. B. Remizov

Book ID: 112488454
Publisher: Springer
Year: 1975
Tongue: English
Weight: 341 KB
Volume: 24
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf01152862

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Using NMR parameters, we have previously reported1 the equilibria that exist between the conformers in trans-4-CF,H3\_.-6-methyl-l,3-dioxanes, (I) + (II). Only free energy differences at 300°K were obtained. Corresponding derivatives with 2-methyl groups also may be equilibrated under acid conditio