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Conformation of the helical polyamide poly(α-isobutyl L-aspartate)

✍ Scribed by Bella, Jordi; Aleman, Carlos; Fernandez-Santin, Jose M.; Alegre, Carme; Subirana, Juan A.

Book ID
126447021
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
673 KB
Volume
25
Category
Article
ISSN
0024-9297

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## Abstract The conformation of poly(α‐L‐aspartic acid) was investigated on a sample in which β‐bonds were not detected. CD and ir spectroscopy showed that poly(α‐L‐aspartic acid) passes through a conformational change induced by changes of the degree of ionization that is accompanied by precipitat

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## Abstract The conformation of several samples of poly(α,β‐L‐Asp) with a molar fraction of β‐bonds ranging from 0.1 to 0.55 was investigated by means of ir and CD spectroscopy and potentiometric titration and compared with the results obtained previously with poly(α‐L‐Asp). All samples investigate