Conformation of Some Terpenoids from Dipole Moment and Nuclear Magnetic Resonance Studies
β Scribed by Bose, A. K.; Manhas, M. S.; Malinowski, E. R.
- Book ID
- 127294753
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 650 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
C chemical shifts and ''P,l'C spin-spin coupling constants are reported for six model phosphinates and eight synthetic phosphinolipids. The complex spectra of the synthetic phosphinolipids could be assigned from increments and couplings derived from the model compounds. Based on these investigations
## Abstract ^1^H NMR spectra are reported for Michler's ketone and twenty of its derivatives, along with ^13^C chemical shifts for five of the compounds. ^1^H chemical shifts show only small changes with increasing substitution at the sterically hindered 2βposition. Estimates of the dihedral angle