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Conformation of cyclic dipeptides. Ab initio calculations on cyclo (glycyl-glycyl), cyclo (D-alanyl-L-alanyl), and cyclo (L-alanyl-L-alanyl)

✍ Scribed by Åse Støgård

Publisher
Wiley (John Wiley & Sons)
Year
1976
Tongue
English
Weight
207 KB
Volume
15
Category
Article
ISSN
0006-3525

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✦ Synopsis

Conformation o f Cyclic Dipeptides. Ab Initio Calculations on cyclo (Glycyl-Glycyl), cyclo (D-Alanyl-L-Alanyl), and cyclo (L-Alanyl-L-Alan y l )

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## Abstract The E~0~ rotamer of __c__‐Gly‐Met has been found to be almost as equally populated as the F rotamer at low temperatures, whereas in __c__‐Gly‐D,L‐Nle and __c__‐Gly‐D,L‐Nvl the F rotamer predominates. The increase of the E~0~ rotamer population parallels the increase of the boat diketopi