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Configurations of the free radicals in irradiated polypropylene and the relation of their decay reactions to the molecular motion

✍ Scribed by Nara, S. ;Kashiwabara, H. ;Sohma, J.


Publisher
Wiley (John Wiley & Sons)
Year
1970
Tongue
English
Weight
47 KB
Volume
8
Category
Article
ISSN
0449-2978

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## Abstract The energy barriers of symmetrical methyl exchanges in the gas phase have been calculated with the reaction path of the intersecting/interacting‐state model (ISM). Reactive bond lengths increase down a column of the Periodic Table and compensate for the decrease in the force constants,