Configurational Stability of Sulfonyl Carbanions Generated by Decarboxylation Reaction
β Scribed by Cram, Donald J.; Wingrove, Alan S.
- Book ID
- 127114257
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 246 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
erroneous report in ref.
The structures of the norbornenyl and norbornyl sulfones more stable than the exo anions. There is good agreement between the optimized structures of the free anions and the exo-5, endo-5 and endo-6 have been determined experimentally, by X-ray analysis, and theoretically by ab experimentally determ
Intermediate dianions formed by nucleophilic attack of methyllithium on a-phenyl or a-phenylthio carboxylate salts fragment in highly coordinating solvents to produce stabilized carbanions. Once formed, these anions may be conveniently functionalized with various electrophilic reagents.