Configuration Energies of the d-Block Elements
โ Scribed by Mann, Joseph B.; Meek, Terry L.; Knight, Eugene T.; Capitani, Joseph F.; Allen, Leland C.
- Book ID
- 125448511
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 74 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Although most neutral d- and f-block atoms have nd(g-2)(n + 1)s(2) and (n - 1)f(g-2)(n + 1)s(2) ground configurations, respectively, where g is the group number (i.e., number of valence electrons), one-third of these 63 atoms prefer a higher d-population, namely via (n + 1)s-->nd "outer" to "inner"
The introduction of an aminoethyl side chain into cyclopenta-plexes with a tethered ammoniumethyl group often show good solubility in protic solvents, relevant with regard to or-dienyl compounds of many d-block elements leads to interesting changes in structure and reactivity compared to the ganomet