Aminoethyl-Functionalized Cyclopentadienyl Complexes of d-Block Elements

✍ Scribed by Peter Jutzi; Thomas Redeker

• Book ID: 102657747
• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 539 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199806)1998:6<663::aid-ejic663>3.0.co;2-y

✦ Synopsis

The introduction of an aminoethyl side chain into cyclopenta-plexes with a tethered ammoniumethyl group often show good solubility in protic solvents, relevant with regard to or-dienyl compounds of many d-block elements leads to interesting changes in structure and reactivity compared to the ganometallic chemistry in water. These features together with others are described in this review, which informs about parent species: (i) A hemilabile bonding situation is observed in complexes with low-valent transition-metal centers; (ii) the synthesis and properties of this new type of transitionmetal complexes. amino-group coordination to an adjacent metal or nonmetal center creates novel types of bimetallic compounds; (iii) com-MICROREVIEWS: This feature introduces the readers to the authors' research through a concise overview of the selected topic. Reference to important work from others in the field is included.