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Configuration and Leishmanicidal Activity of (−)-Argentilactone Epoxides

✍ Scribed by Cortés, Manuel J.; Armstrong, Veronica; Barrero, Alejandro F.; Bandoni, Arnaldo E.; Priestap, Horacio A.; Fournet, Alain; Prina, Eric

Book ID
127338872
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
138 KB
Volume
20
Category
Article
ISSN
1478-6419

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✍ Muhammad Saeed; Thomas Ilg; Miriam Schick; Muhammad Abbas; Wolfgang Voelter 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 78 KB

Starting from the commercially available D-glucal (2), the naturally occurring a,b-unsaturated d-lactone argentilactone (1a) has been synthesized. The important step is the configuration inversion at C-6 by the Mitsunobu reaction following the sugar-non-sugar-sugar strategy. The synthetic argentilac