Conducting polymer-based ion-selective electrodes
β Scribed by Jan Migdalski; Teresa Blaz; Andrzej Lewenstam
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 746 KB
- Volume
- 322
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
Single-piece, conducting polymer-based, potentiometric sensors with enhanced cationic sensitivity were obtained by doping a polypyrrole with metal-complexing, niultivalent anions. Sulphosalycilic acid, Tiron, Eriochrome Black T and Kalces have been used as doping ions. Predominant sensitivity for copper was observed for the first two dopants, whereas for the two remaining ones, induced response for magnesium and calcium was found, respectively. Interestingly, in all sensors studied the metal-binding properties of the specific ligands known from polar solvents were retained. Hence, the specific reagents can be deliberately utilized for the construction of conducting polymer-based ion-selective sensors.
π SIMILAR VOLUMES
Neutral-carrier-based ion-selective electrodes for the assay of alkali and alkaline earth metal cations have advanced to become the most frequently used potentiometric sensors in clinical chemistry . The major developments since the realization of the first potentiometric cell assemblies utilizing e
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Polypyrrole-based solid-state redox supercapacitors have been constructed using proton and lithium ion conducting polymer electrolytes : poly(vinyl alcohol) and poly(ethylene oxide) (PVA)ΓH 3 PO 4 , (PEO)ΓLiCF 3 SO 3 plasticized with poly(ethylene glycol) (PEG). The capacitors have been characterize