Conditional Monte Carlo Sampling To Find Branching Architectures of Polymers from Radical Polymerizations with Transfer to Polymer
β Scribed by Iedema, Piet D.; Hoefsloot, Huub C. J.
- Book ID
- 127383214
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 150 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Dependencies of PDI on monomer conversion (a = ([M] 0 -[M])/[M] 0 ) for systems with [M] 0 /[I] 0 = 10 2 , computed for various (shown in the Figure) values of (k tr / k p ) N ([M] 0 /[I] 0 ). Dotted lines: systems without disproportionation (Ref. [1] ), circles: systems with disproportionation.
## Abstract **Summary:** Polymer molecules made by radical polymerization with transfer to polymer and recombination termination contain branch points (connecting branch arms to backbones) and combination points (connecting various molecular structures). The trivariate chain length/degree of branch