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Condensations. XV. 1 The Electronic Mechanism of the Diazo Coupling Reaction 2

โœ Scribed by Hauser, Charles R.; Breslow, David S.


Book ID
126799959
Publisher
American Chemical Society
Year
1941
Tongue
English
Weight
322 KB
Volume
63
Category
Article
ISSN
0002-7863

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This calculation introduces a promising way to catalyze gas-phase S N 2 reactions at a unimolecular level by using an excess electron (EE) as an ''electron solvent''. The EE participation leads to very favorable energetics for the reaction, by neutralizing the created positive charge as the reaction