## Abstract Diisocyanates condense readily with the two active hydrogen atoms in dioximes to give high molecular weight linear condensation polymers. In several cases these polymers, such as the one from cyclohexanedione dioxime and 4,4′‐biphenylene diisocyanate, magnified image may be converted to
Condensation polymers from diphenols and glyoxal
✍ Scribed by Ayşegül Acuner Tunca; Okan Sírkecíoǧlu; Nacíye Talinli; Ahmet Akar
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 326 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
AbstracGPolycondensation
of biphenols such as 2,2-di(4-hydroxyphenyl) propane, I-phenyl-l,l-di(C hydroxyphenyl) ethane, l,l-di(4-hydroxyphenyl) cyclohexane and dihydroxynaphthalenes with glyoxal resulted in a ladder type of polymers. The structures of the ladder polymers were elucidated by FTIR and 'H-NMR.
📜 SIMILAR VOLUMES
The versatility of the reaction of the isocyaiiate group with various active hydrogen compounds, and some polymers made by this type of reaction, have been discussed recently. Among the unusual active hydrogen compounds which have not been adequately investigated as polymer formers with diisocyanate
A mixture of bis-aminal isomers was obtained from aqueous glyoxal-triethylenetetraamine condensation. The irreversible isomerization of the species was observed and a new synthesis of cyclen proposed.