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Condensation of triformylmethane with adenosine: novel cyclic adducts derived from 1,3-dicarbonyl compounds


Book ID
120639690
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
125 KB
Volume
1
Category
Article
ISSN
1472-779X

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Mild air-oxidation of 1,3-dicarbonyl com
✍ Toshiko Watanabe; Tsutomu Ishikawa πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 231 KB

1,3-Dicarbonyl eompomids (1) were efficiently oxygetmted at the or-position with cesium salts, such as CsF or Cs2CO3 (0. l Meq) ill DMF at room temperature. Reaction of malonate derivatives (la, b) with excess amount (2 Meq) of Cs2CO3 gave ~t-hydroxyhnonoester (3) formed by oxygenation and partial h