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Condensation of Saturated Hydrocarbons with Haloöefins. II. The Reaction of Isobutane with cis- and trans-Dichloroethylene

✍ Scribed by Schmerling, Louis

Book ID
126191818
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
350 KB
Volume
70
Category
Article
ISSN
0002-7863

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Cis and trans 1,2dichloroethylene react with LiPPha [l] and LiAsPha [2, 31 stereospecifically to form the corresponding vinylic diphosphines and diarsines in high yield. However cis 1,2dichloroethylene and NaAsMea produce 1,2-bis(dimethylarsino)ethylene, MeaAsCH = CHAsMea, in approximately 30% with