The Products of the Reactions of Sodium t-Butylmercaptide with Vinyl Chloride, Vinylidene Chloride, and cis- and trans-Dichloroethylenes 1,2
โ Scribed by Flynn, John; Badiger, Virupax V.; Truce, William E.
- Book ID
- 126955553
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 723 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Cis and trans 1,2dichloroethylene react with LiPPha [l] and LiAsPha [2, 31 stereospecifically to form the corresponding vinylic diphosphines and diarsines in high yield. However cis 1,2dichloroethylene and NaAsMea produce 1,2-bis(dimethylarsino)ethylene, MeaAsCH = CHAsMea, in approximately 30% with
Kinetic studies on reactions of ozone with trans-1,2-dichloroethene (DCE) and vinyl chloride (VC) were performed in air. In the presence of scavengers of radicals, such as CHBCHO, the rates for both reactions are second order (first order in each reactant). Observed rate constants are (1.80 f 0.29)