๐”– Bobbio Scriptorium
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Condensation of poly(4-vinylacetophenone) with various araldehydes

โœ Scribed by C. C. Unruh; A. C. Smith Jr.


Publisher
John Wiley and Sons
Year
1960
Tongue
English
Weight
539 KB
Volume
3
Category
Article
ISSN
0021-8995

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Films made from poly(styrene) hydroperoxide (PSOOH) and poly(vinylacetophenone) (PVAP) were exposed to long-wave (2/> 300 nm) u.v. radiation under high vacuum at 25 + I ยฐ. The presence of PVAP considerably enhanced the rate of decomposition of PSOOH, the quantum yield increasing by a factor of 2.5.

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The photochemistry of isotopically labelled poly(vinylacetophenone) (PVAP) has been investigated, with a view to determining the point of H-atom abstraction from the polymer. Poly(ct-Dvinylacetophenone) (DPVAP) and poly [3.[3 dideuterovinyl(acetophenone) (D2PVAP) were irradiated under high vacuum wi