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Concise Total Synthesis of (−)-Myxalamide A

✍ Scribed by Kazuhiro Fujita; Dr. Ryosuke Matsui; Dr. Takahiro Suzuki; Prof. Dr. Susumu Kobayashi

Book ID
111951001
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
391 KB
Volume
51
Category
Article
ISSN
0044-8249

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## Abstract For Abstract see ChemInform Abstract in Full Text.

A Concise Total Synthesis of (+)-Heliotr
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## Abstract A practical synthesis of the necine base (+)‐heliotridine (**1**) is reported here. The present total synthesis is based on the highly selective 1,3‐dipolar cycloaddition of (__S__)‐3‐__tert__‐butoxypyrroline __N__‐oxide (**2**) to the commercially available ethyl 4‐bromocrotonate, foll