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Concise Catalytic Asymmetric Total Synthesis of Biologically Active Tropane Alkaloids

✍ Scribed by Armando Córdova; Shuangzheng Lin; Abrehet Tseggai

Book ID
111992646
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
472 KB
Volume
354
Category
Article
ISSN
1615-4150

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✍ Yongcheng Song; Sentaro Okamoto; Fumie Sato 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 112 KB

A general access to 5,8-disubstituted indolizidine alkaloids has been developed, where the asymmetric addition of an optically active allenyltitanium to benzyl[4-(tert-butyldimethylsilyloxy)butylidene]amine (2) is the key reaction. As a typical example, (-)-indolizidine 209B was efficiently synthesi