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Concerted vs Stepwise Mechanisms in Dehydro-Diels–Alder Reactions

✍ Scribed by Ajaz, Aida; Bradley, Alexander Z.; Burrell, Richard C.; Li, William Hoi Hong; Daoust, Kimberly J.; Bovee, Laura Boddington; DiRico, Kenneth J.; Johnson, Richard P.

Book ID
118052956
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
873 KB
Volume
76
Category
Article
ISSN
0022-3263

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Vmylacetylene 1 undergoes reactions with dienopNles by a mechanism involving initial addition of acids to the triple bond, cycloaddition, and elimination of add. For more than half a century the fact that vinylacetylenes can undergo cycloaddition reaclions with dienophiles ("dehydro Die&Alder reacti