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Concerning the Role of Protonated Cyclopropane Intermediates in Solvolytic Reactions. I. The Solvolysis of Cyclopropane in Deuteriosulfuric Acid

✍ Scribed by Baird, Richard L.; Aboderin, Akintola A.

Book ID
126795682
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
611 KB
Volume
86
Category
Article
ISSN
0002-7863

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## Abstract The rates of solvolysis of propylene and cyclopropane in 6.49__M__ H~2~SO~4~ have been measured as a function of temperature. From the data, calculations of the relative heats of formation in solution of the 2‐propyl cation and protonated cyclopropane have been made. The heat of formati