Concerning the Mechanisms of Alkylamine Diazotization and N-Alkyl-N-nitrosoacetamide Decomposition
โ Scribed by Bayless, John H.; Friedman, Lester.
- Book ID
- 126200820
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 224 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The tripeptide alanylalanylalanine reacts with either HOCl or HOBr to form a N, Ndihalopeptide. These compounds decompose to the N-halo-N'-(a-iminoket0)peptides plus halide ion. The rate constants for these reactions in 0.4-M NaCl were determined to be (PH 6.7) k4 = 1.06 x 1015e 18,400'RT min-' (PH
At 298 K the rate constant for the decomposition of N-chloroleucine has the constant value 3.20 >: lo-\* s-' over the range pH 5-12, increases with increasing acidity at pH < 5, and increases with pH a t pH > 12. A mechanism is put forward which explains these results.