Ihe rate of dlffusional encounters betaeen two species confined painvise in small spherical volumes is imestigated by mezms of compu:er simulation and approximate analytical analysis. Such sysiems consisting of cage type subsystems uith two reactants occur in the case of micekr solubilized partners
Concerning some widespread errors in diffusion-controlled reaction kinetics
β Scribed by K. Razi Naqvi
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 110 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
This premise has also been adopted by workers studying membranes, where diffusion is (assumed to be) confiied to a pkne [lO,lll-205 V&nttr 67. number I CIII-SIICAL PIIYSIC-S Lt -I-II;KS I _\o\imlrc-r 19i9 206
π SIMILAR VOLUMES
S~~~YIUI~ from the generalized theory of blmolwlar diffusion-controlled reactiorus betwatn reagents in soli& and liquids, we have performed calculations of Lhe A+B \* AB (F'renkel defecL anmhilalion) and A+A + B (exciton annihdation) reaction kinetics over a wide time interval and for high initial c
Fluorescence data-emission intensities and decay profiles of benzyl 1-pyrenoate in the presence of dimethylaniline in anionic homomicelles and in mixed micelles have been analyzed with two different models: a kinetic model of diffusion-controlled reactions in micelles with a reflecting boundary surf