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Computer calculation of liquid-junction potentials—II. Junction potentials for junctions with concentrated KCl

✍ Scribed by John Bagg

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
391 KB
Volume
35
Category
Article
ISSN
0013-4686

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📜 SIMILAR VOLUMES

Computer calculation of liquid-junction
Computer calculation of liquid-junction potentials—I. Concentration profiles at junctions with concentrated KCl
✍ John Bagg 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 455 KB

A numerical method has been used to simulate the junction Z (0.001-6 M) (( KCI (4 M), where Z is (a) HCI or an alkali halide with an ion in common with KC1 or (b) CaCI,, LaCI,, or K,SO,. By applying diffusion equations to this simulation the ionic concentration profiles have been determined. The dif

Computer calculation of liquid-junction
Computer calculation of liquid-junction potentials—III. Temperature-dependence of junction potentials
✍ John Bagg 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 500 KB

Junction potenuals for KCl(4M)IIX where X IS one of N&l, L&l, NaOH, HCl, L@04, Ms(NO,h, L&l, ran8mg m concentration from 0 001 to 4 M have been calculated at 0,25, 100°C by usmg the emulation and numerical methods of Parts I and II [J. Bagg, Ekctrochim Acta 3!!, 361, 367 (1990)] Junction pot@& range

The definition and measurement of the di
The definition and measurement of the diffusion potential for liquid junctions between molten electrolytes
✍ A.J. Easteal 📂 Article 📅 1966 🏛 Elsevier Science 🌐 English ⚖ 184 KB

THE diffusion potential arises from differences in the mobilities of ions at the junction between two non-identical electrolytic conductors. It is thus that contribution, to the emf of a concentration cell with transference, arising from irreversible diffusion processes taking place at the liquid ju