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The definition and measurement of the diffusion potential for liquid junctions between molten electrolytes

โœ Scribed by A.J. Easteal

Publisher
Elsevier Science
Year
1966
Tongue
English
Weight
184 KB
Volume
11
Category
Article
ISSN
0013-4686

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โœฆ Synopsis

THE diffusion potential arises from differences in the mobilities of ions at the junction between two non-identical electrolytic conductors. It is thus that contribution, to the emf of a concentration cell with transference, arising from irreversible diffusion processes taking place at the liquid junction of the cell. The general expression for the "true" diffusion potential is

๐Ÿ“œ SIMILAR VOLUMES

A study of the contribution of solvent t
A study of the contribution of solvent transport to liquid junction potentials between electrolytes in different solvents
โœ R.C. Murray Jr.; D.A. Aikens ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 981 KB

AImtract-Meamrements have been made on cells which contain liquid junctions between two solutions containing different solvents. By employing cells in which the two solutions are saturated with the same salt, it has been possible to directly measure the contribution to the liquid junction potential