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Computational View of the Mechanism of Vinylphosphirane Pyrolysis and a New Route to Phosphaalkynes

✍ Scribed by Berger, Daniel J.; Gaspar, Peter P.; LeFloch, Pascal; Mathey, Francois; Grev, Roger S.

Book ID
127354110
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
342 KB
Volume
15
Category
Article
ISSN
0276-7333

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## Abstract The previously reported extensive mechanism for the pyrolysis of propane and __n__‐butane around 800 K is reexamined in the light of a recent reevaluation of the rate constant data base, and the sensitivity of model simulations to variations in the rate parameters is studied. The pyroly