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Computational study of fluxional hydride bridged binuclear transition metal complexes: Effect of secondary bridging ligands

✍ Scribed by Brandon J. Burkhart; Roger L. DeKock


Book ID
116380187
Publisher
Elsevier
Year
2012
Tongue
English
Weight
564 KB
Volume
994
Category
Article
ISSN
2210-271X

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Metathesis reactions of dinuclear halo-bridged complexes of the late transition metals have been studied by NMR. For selected combinations of 15 different complexes, it has been shown that asymmetric complexes are formed in a dynamic equilibrium. The equilibrium constants have been calculated and th